500e702u, based on what you’re describing thus far, it does sound like it might be an issue with a partially collapsing tank. Hopefully not? But there’s honestly only one way to find out: removing the tank for an inspection. Before that, though, you could also have a smoke test done to see if there are any leaks or pressure inconsistencies. I had my Master Tech do that for me, and while nothing turned up initially, a week later we removed the tank and found the entire backside to be collapsed. And yes, if you’re wondering, that sort of thing is pretty much impossible to repair.
The most common cause for a collapse, or preliminary hairline fractures, is a clogged vent valve. It’s a small white plastic little thing that costs pretty much nothing, but has the potential to ruin an entire tank if not cleaned regularly, or, more responsibly, just replaced. It’s beyond strange(and disappointing) that Mercedes didn’t address that issue during initial testing of the 500, because the issue seems to be directly related to the tank and vent valve being originally designed to handle the pressure generated from a smaller engine—not necessarily the monster V8 that got dropped in. Or at least, that’s what a few of the Master Techs at Fletcher Jones concluded after a long study of my situation.
So, yes, as gsxr already noted, you 100% need to replace the vent valve. It should honestly be at the top of any list of mandatory maintenance for our cars. Why? Because you can’t buy the original 90L tanks new from MB anymore. They unfortunately confirmed with me last year that they sent me the last one. And because it’s illegal in most(all?) states to ship used tanks, the only way to replace a tank with a used one is to find someone(preferably here) that you can trust, and has one available, is within driving distance, and is willing to part with it. Or, as was already mentioned, you can easily put in the smaller 70L tank without any problems—at least until you track down a 90L one.
gsxr had also suggested to me that I go ahead and inspect and replace all sorts of other fuel-related pieces while I was in deep and had the tank out—an excellent idea that ended up giving me peace of mind when trying to get rid of the lingering fuel smell after it was all over. The simplest, cheapest thing to replace: the O rings on the tank! Especially the ones for the fuel sender. Those rings age and thin over time(especially 30 years later). When worn out, the slightest turn while driving can lead to fuel leaking out of there. Even the smallest drop can yield a very strong fuel smell in the trunk and cabin, and you won’t even necessarily see a puddle under the tank.
If you’re curious, in addition to installing a brand new tank, and new vent valve, I also went and changed all the fuel lines, breather line, purge valve, charcoal canister, fuel pumps, and gas cap. Also, I removed all of the trunk lining, rear seat, and floor carpet, and deep cleaned every inch. Hopefully you don’t have to go to those lengths, ha. Best of luck to ya!