The button referred to by
@BRABUS124 as the “defrost” button in the middle row on the two zone klima is not a defrost button. That button activates the drying function of the ac system, and is supposed to remove moist on the inside of the windows. The drying function will start under certain circumstances by itself, but is possible to activate manually if needed. It’s all in the owners manual, albeit poorly translated and a bit confusing, the German original is way better:
View attachment 183911
On the topic on how the middle vents operate, on my 420 they were the same temperature as all other vents when using the ac (not pressed in EC button). On the 500 I have to check. On older 124’s I had, with or without ac, they are outside temp so needs to be closed otherwise it will be a bit chilly inside. I do now also own a 300E after my dads passing, and that car has the full fat klima, I’ll test on that car too, once I get it assembled again, but that’s another story!