So what didn't go to plan yesterday(?)
First was from working 100% above only removing a knock sensor wire was difficult. I could not depress the clip and pull on it at same time reaching down from above. Solution was to cable tie a cable to it, pull the white tie with pliers whilst depressing the clip with needle nose pliers. Worked perfect
2nd issue was pulling a chain guide pin. When removing them in car before I have always successfully used a m6 threaded bar, socket and washer / nut technique. Not this time!!! Broke 4x bolts off trying to pull it and it would not budge.
Ended up putting together a make shift slide hammer and even with that had to hit it as hard as I could whilst protecting the radiator with a steel plate and rags. It did come out after heating head and hamering like F. Never had one like that before.

I have since ordered a special MB slide pin slide hammer tool for use within engine compartment so I don't run into this again! (I think you need a slide hammer really the puller doesn't always work)
Third problem was splitting the chain. Turns out my de pinner tool must only be for diesel chains and was only about 0.2mm too wide. Before I noticed I had damaged a link. So to be safe I will replace the timing chain altogether. There was a little stretch in the chain so may have went that route anyway.
So yeah she put up a fight but it was off with her head anyway! Just took about 4 hours longer than it should have. Still overall quite an easy task and the water pump etc all stayed on just worked around them.
I will phone the machine shop tomorrow just to see if they can fit the S320 head in for a spa trip. (Hot tank, valve lap all that good stuff) If they are too busy I will proceed to clean it myself instead - I do not want this dragging on for months. Besides that this S320 always ran superb this was really only to address the head gasket oil leaks. But for the sake for a few extra £ would rather they took care of the head when it's off so will see what they say tomorrow and if they can take it soon.