The "Positive cable" for your E420 based on the VIN you gave is a part number 124 540 31 30.
I sourced wire locally and got silicone jacketed stranded copper wherever I could. It means you may have to buy a small spool of the stuff, but it's still cheaper than buying a new harness (if that's even an option.) I reused the heavy stuff if it was in good shape. It's been my experience, albeit limited, that the larger cables are usually fine when it comes to insulation. it's the smaller signal and low current leads that seemed to be the most affected by insulation breakdown.
If it was sockets or pins that were soldered, I desoldered them from the old harness, cleaned them up and reused them. No reason not to, they're quite sturdy. I have a pile of pins in my parts collection, so I had spares in the event one was damaged. Depending on the application, there were usually some large ring terminals for the connections to the starter, which I just got from the "magic boxes" at my local Ace hardware. Besides crimping these I soldered them, too.
Also get an assortment of heat shrink tubing for covering terminals when required. If there was a jacket/sleeve along a length of the cable, as there is on the W140 harnesses, I got some high temperature wiring harness jacket material from the Island of Large Wimmen. Good stuff to have on hand, too.
Take the old harness, lay it out on the bench, and lay out your new wires next to it to match length and configuration. Move terminals from the old harness to the new one one at a time. This can be tedious, but it assures that you don't mix anything up. Be careful to recover any grommets or brackets and assemble them into the new harness in the proper location as well.
It's not brain surgery, you just need to be meticulous and take your time.
If you're doing an 034, it's a good idea to tie a piece of string or light wire to the old harness when removing it so you have something to "fish" the rebuilt harness into the holes in the chassis. Otherwise, it's a real pain to wrestle the new and usually quite rigid new wires into the opening and down into the chassis.
Dan